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Dope it with germanium: selective access to functionalized Si5Ge heterocycles.
- Source :
- Chemical Communications; 1/18/2023, Vol. 59 Issue 6, p716-719, 4p
- Publication Year :
- 2023
-
Abstract
- The Cl<superscript>−</superscript> diadduct [nBu<subscript>4</subscript>N]<subscript>2</subscript>[A·2Cl] of the mixed cyclohexatetrelane (SiCl<subscript>2</subscript>)<subscript>5</subscript>(GeMe<subscript>2</subscript>), A, is accessible from Me<subscript>2</subscript>GeCl<subscript>2</subscript>, 6 eq. Si<subscript>2</subscript>Cl<subscript>6</subscript>, and 2 eq. [nBu<subscript>4</subscript>N]Cl in one step (96%). Free, tenfold functionalized A can be released from the primary product by decomplexation with AlCl<subscript>3</subscript> (78%). Insight into the assembly mechanism of [nBu<subscript>4</subscript>N]<subscript>2</subscript>[A·2Cl] and the reactivity of A is provided. [ABSTRACT FROM AUTHOR]
- Subjects :
- GERMANIUM
HETEROCYCLIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 161339178
- Full Text :
- https://doi.org/10.1039/d2cc06060d