Highly Selective Nitrogen-Doped Graphene Quantum Dots/Eriochrome Cyanine Composite Photocatalyst for NADH Regeneration and Coupling of Benzylamine in Aerobic Condition under Solar Light.

Photocatalysis is an ecofriendly and sustainable pathway for utilizing solar energy to convert organic molecules. In this context, using solar light responsive graphene-based materials for C–N bond activation and coenzyme regeneration (nicotinamide adenine dinucleotide hydrogen; NADH) is one of the utmost important and challenging tasks in this century. Herein, we report the synthesis of nitrogen-doped graphene quantum dots (NGQDs)-eriochrome cyanine (EC) solar light active highly efficient "NGQDs@EC" composite photocatalyst for the conversion of 4-chloro benzylamine into 4-chloro benzylamine, accompanied by the regeneration of NADH from NAD⁺, respectively. The NGQDs@EC composite photocatalyst system is utilized in a highly efficient and stereospecific solar light responsive manner, leading to the conversion of imine (98.5%) and NADH regeneration (55%) in comparison to NGQDs. The present research work highlights the improvements in the use of NGQDs@EC composite photocatalyst for stereospecific NADH regeneration and conversion of imine under solar light. [ABSTRACT FROM AUTHOR]