Key Role of Arctic Sea‐Ice in Subseasonal Reversal of Early and Late Winter PM2.5 Concentration Anomalies Over the North China Plain.

The PM2.5 (fine particulate matter with diameter ≤2.5 μm) concentration anomalies over the North China Plain (NCP) in early and late winter sometimes show a subseasonal reversal, which brings a great challenge for precise control of air pollution, and mechanisms are not well understood. This paper reveals the key role of the Barents Sea sea‐ice in this reversal. In early winter, a negative Scandinavian‐like pattern causes an anticyclonic anomaly over Northeast Asia and thus leads to the positive PM2.5 concentration anomaly over the NCP. In addition, anomalous warm advection associated with the positive North Atlantic Oscillation‐like pattern accelerates winter sea‐ice loss in the Barents Sea, especially in late winter, which increases the surface turbulent heating flux. These heating causes a negative Polar/Eurasian‐like pattern that induces a cyclonic anomaly over Northeast Asia and eventually leads to a negative PM2.5 concentration anomaly over the NCP in late winter. Vice versa. Plain Language Summary: In this study, we find that there is a significant seesaw pattern of PM2.5 concentration anomalies over the North China Plain (NCP) in early and late winter. Further results reveal that variations in Barents Sea sea‐ice play a crucial role. More specifically, a negative (positive) Scandinavian‐like pattern in early winter tends to induce an anticyclonic (a cyclonic) anomaly over Northeast Asia. This anticyclonic (cyclonic) anomaly leads to a higher (lower) PM2.5 concentration anomaly over the NCP in early winter. In addition, a North Atlantic Oscillation‐related warm (cold) temperature advection promotes (inhibits) the sea‐ice loss in the Barents Sea, especially in late winter. The Barents Sea‐ice loss (increment) in late winter tends to heat (cool) the lower‐level atmosphere and thus triggers an anticyclonic (a cyclonic) response in the upper troposphere there. The anticyclonic (cyclonic) response in the Barents Sea region as a part of the negative (positive) Polar/Eurasian‐like pattern induces a cyclonic (an anticyclonic) anomaly over Northeast Asia, which leads to a lower (higher) PM2.5 concentration anomaly over the NCP in late winter. These findings could be of great value for the subseasonal predictions of PM2.5 concentrations over the NCP in winter. Key Points: PM2.5 concentration anomaly over the North China Plain shows an visibly subseasonal reversal in early and late winter on interannual scaleThe Scandinavia‐like pattern and Polar/Eurasian‐like pattern are responsible for the seesaw pattern of PM2.5 concentration anomaliesThe sea‐ice variations in the Barents Sea play a key role in modulating such atmospheric circulations [ABSTRACT FROM AUTHOR]