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Graphene‐Oxide Mediated Chemodivergent Ring‐Opening of Cyclobutanols.

Authors :
Brunetti, Andrea
Pintus, Angela
Lombardi, Lorenzo
Kovtun, Alessandro
Mascietti, Federico
Bruno, Francesco
Ravera, Enrico
Melucci, Manuela
Bertuzzi, Giulio
Bandini, Marco
Source :
Chinese Journal of Chemistry; Jun2023, Vol. 41 Issue 11, p1333-1340, 8p
Publication Year :
2023

Abstract

Comprehensive Summary: The chemodivergent ring‐opening of cyclobutanols is described under the carbocatalytic assistance of graphene oxide (GO). The protocol enables the synthesis of diversely functionalized dienes or indenes (26 examples) based on the amount of GO employed. Spectroscopic (XPS and ssNMR) as well as experimental investigations revealed a direct involvement of the π‐domains of GO in tuning the stability of carbocationic intermediates during the reaction. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1001604X
Volume :
41
Issue :
11
Database :
Complementary Index
Journal :
Chinese Journal of Chemistry
Publication Type :
Academic Journal
Accession number :
163411131
Full Text :
https://doi.org/10.1002/cjoc.202200757