Back to Search
Start Over
Chiral Boro‐Phosphate Catalyzed Asymmetric Transfer Hydrogenation of 1‐Enal Substituted 2‐Naphthols: Access to Axially Chiral Styrene‐Type Allylalcohols.
- Source :
- Advanced Synthesis & Catalysis; 5/12/2023, Vol. 365 Issue 9, p1398-1404, 7p
- Publication Year :
- 2023
-
Abstract
- Herein, we present a chiral boro‐phosphate catalyzed atroposelective asymmetric transfer hydrogenation method, leading to a family of axially chiral styrene‐type allylalcohols. This dynamic kinetic resolution approach portrays simple procedure, mild conditions and good enantiocontrol (51–95% ee), thus providing an important alternative to assemble the challenging atropisomeric aryl‐acyclic alkene scaffolds. [ABSTRACT FROM AUTHOR]
- Subjects :
- TRANSFER hydrogenation
CHIRALITY element
ALKENES
HYDROGENATION
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 365
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 163705186
- Full Text :
- https://doi.org/10.1002/adsc.202300042