Insight into the pollution characteristics of road and roof runoff in Changsha, China.

Non-point source pollution from rainwater runoff presents a serious challenge for urban water management in many cities undergoing urbanization and experiencing climate change. To alleviate water resource conflicts in Changsha, China, this study comprehensively evaluated the pollution characteristics and first flush effect (FFE) of runoff from asphalt roads and colored steel plate roofs under seven rainfall events in April–May 2022. The runoff was collected and purified using bioretention ponds. The results showed that the peak runoff pollutant concentrations occurred within the first 20 min of runoff generation and then decreased to relatively stable levels, with maximum total suspended solids (TSS) concentration and chemical oxygen demand (COD_Cr) reaching 873.5 and 207.32 mg/L, respectively, for road runoff and 162 and 73.31 mg/L for roof runoff, respectively. The main pollutants were TSS and COD_Cr, followed by ammonia nitrogen (NH₄⁺-N), nitrate nitrogen (NO₃⁻-N), total phosphorus (TP), and nitrite nitrogen (NO₂⁻-N). Concentrations of pollutants and FFE for roof runoff were lower than those for road runoff. Road runoff had a more obvious FFE for TP and NH₄⁺-N, whereas the roof runoff showed the presence of TP and NO₃⁻−N. An important implication is that treating the first 30% of surface runoff from rainfall events with long antecedent dry days or high rainfall amounts is necessary to improve water quality before discharge or utilization. The study also found that road and roof runoff, after treatment with bioretention ponds, exhibit good water quality, thus, allowing their use as reclaimed water or for miscellaneous purposes in urban areas. Overall, this study provides useful information for designing management measures to mitigate runoff pollution and reuse in Changsha. [ABSTRACT FROM AUTHOR]