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Efficient C2H2-selective separation in a microporous Zn(II)-based metal–organic framework via the dual-ligand strategy.
- Source :
- Chemical Communications; 5/25/2023, Vol. 59 Issue 42, p6403-6406, 4p
- Publication Year :
- 2023
-
Abstract
- Implementing the dual-ligand strategy, a microporous Zn-based MOF 1 with nitro and amino groups was effectively produced. The activated interconnected pores of 1 exhibited high C<subscript>2</subscript>H<subscript>2</subscript> uptake capacity and preferential adsorption behaviour for C<subscript>2</subscript>H<subscript>2</subscript> over CO<subscript>2</subscript>, as identified by the experiments and simulations. This work provides a new approach for designing and synthesizing the MOFs with desired structures and properties by optimizing their pore environment via the dual-ligand strategy. [ABSTRACT FROM AUTHOR]
- Subjects :
- METAL-organic frameworks
AMINO group
GROUP 15 elements
ADSORPTION capacity
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 42
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 163874693
- Full Text :
- https://doi.org/10.1039/d3cc01566a