Exceptional Wildfire Enhancements of PAN, C2H4, CH3OH, and HCOOH Over the Canadian High Arctic During August 2017.

Extreme enhancements in the total columns of carbon monoxide (CO), peroxyacetyl nitrate (PAN), ethylene (C2H4), methanol (CH3OH), and formic acid (HCOOH) were observed over the Canadian high Arctic during the period of 17–22 August 2017 by a ground‐based Fourier transform infrared (FTIR) spectrometer at Eureka, Nunavut (80.05°N, 86.42°W), and by the Infrared Atmospheric Sounding Interferometer (IASI) satellite instruments. These enhancements have been attributed to wildfires in British Columbia (BC) and the Northwest Territories (NWT) of Canada, and represent the largest short‐term perturbations of PAN, C2H4, and HCOOH above ambient concentrations over the 14‐year (2006–2020) Eureka time‐series. Enhancement ratios, emission ratios, and emission factors relative to CO were calculated for all species for both FTIR and IASI observations. The C2H4 and HCOOH emission factors are significantly larger than previous studies, suggesting unusually high emissions from these fires. The wildfire plumes were also simulated using the GEOS‐Chem model. Initial GEOS‐Chem simulations displayed a severe under‐estimation relative to observations for these fire plumes resulting from the injection height scheme of the model. Sensitivity tests highlighted that injection heights of 12.5 km for BC (based on previous studies) and 10 km for the NWT fires yielded the strongest correlations with ground‐based measurements. Applying these injection heights to the model significantly improves the simulated plume transport and agreement with ground‐ and space‐based observations. GEOS‐Chem was also used to estimate the magnitude of secondary in‐plume production of CH3OH and HCOOH; it was found to be an important component (∼18%) of the enhanced HCOOH columns at Eureka. Plain Language Summary: Wildfires are a significant natural source of pollution to the atmosphere. During mid‐August 2017, two extremely large wildfires occurred simultaneously in British Columbia (BC) and the Northwest Territories (NWT) of Canada. These fires produced an exceptional amount of smoke, which was subsequently transported to the Canadian high Arctic region. The atmospheric concentrations of carbon monoxide (CO), peroxyacetyl nitrate (PAN), ethylene (C2H4), methanol (CH3OH), and formic acid (HCOOH) contained within these transported smoke plumes were measured using both a ground‐based infrared spectrometer located at Eureka, Nunavut (80.05°N, 86.42°W) and satellite instruments. The largest concentrations of CO, PAN, C2H4, and HCOOH observed over the 14‐year measurement record (2006–2020) of the ground‐based spectrometer were due to these wildfires. The emissions of these fires were estimated from both the ground‐ and space‐based measurements and were found to be unusually high in comparison to previous studies. The wildfire smoke plumes were also simulated using a chemical transport model, but the model was found to inject the smoke too low into the atmosphere above the fires; after adjustments to the injection scheme were made, the agreement of the model with the measurements was significantly improved. Key Points: The 2017 Canadian wildfires produced the largest PAN, C2H4, and HCOOH column enhancements observed in the high Arctic from 2006 to 2020GEOS‐Chem effectively simulates the observed plume transport, but required modifications to the injection heights of the fire emissionsMid‐latitude wildfires may become an increasingly significant source of reactive VOC species to the high Arctic during the summer months [ABSTRACT FROM AUTHOR]