The Enhancement of CO Oxidation Performance and Stability in SO 2 and H 2 S Environment on Pd-Au/FeO X /Al 2 O 3 Catalysts.

Carbon monoxide (CO) is a colourless, odourless, and toxic gas. Long-term exposure to high concentrations of CO causes poisoning and even death; therefore, CO removal is particularly important. Current research has focused on the efficient and rapid removal of CO via low-temperature (ambient) catalytic oxidation. Gold nanoparticles are widely used catalysts for the high-efficiency removal of high concentrations of CO at ambient temperature. However, easy poisoning and inactivation due to the presence of SO₂ and H₂S affect its activity and practical application. In this study, a bimetallic catalyst, Pd-Au/FeO_x/Al₂O₃, with a Au:Pd ratio of 2:1 (wt%) was formed by adding Pd nanoparticles to a highly active Au/FeO_x/Al₂O₃ catalyst. Its analysis and characterisation proved that it has improved catalytic activity for CO oxidation and excellent stability. A total conversion of 2500 ppm of CO at −30 °C was achieved. Furthermore, at ambient temperature and a volume space velocity of 13,000 h⁻¹, 20,000 ppm CO was fully converted and maintained for 132 min. Density functional theory (DFT) calculations and in situ FTIR analysis revealed that Pd-Au/FeO_x/Al₂O₃ exhibited stronger resistance to SO₂ and H₂S adsorption than the Au/FeO_x/Al₂O₃ catalyst. This study provides a reference for the practical application of a CO catalyst with high performance and high environmental stability. [ABSTRACT FROM AUTHOR]