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SnSe nanosheet hybridized with reduced graphene oxide for enhanced hydrogen revolution reaction.

Authors :
Li, Changle
Qiao, Hui
Liu, Yundan
Huang, Zongyu
Luo, Siwei
Wang, Ziyu
Qi, Xiang
Source :
Applied Physics A: Materials Science & Processing; Jun2023, Vol. 129 Issue 6, p1-8, 8p, 2 Black and White Photographs, 1 Diagram, 1 Chart, 4 Graphs
Publication Year :
2023

Abstract

SnSe with layered structure, as a member of 2D materials and transition metal chalcogenides, is a promising candidate of electrocatalyst for hydrogen evolution. Reduced graphene oxide (RGO) is an excellent substrate of electrocatalyst. In this work, SnSe nanosheets (NSs) had been prepared via liquid exfoliation, and the as-prepared SnSe NSs had been hybridized with RGO by a simple hydrothermal method. The SnSe/RGO hybrid shows superior hydrogen evolution reaction (HER) performance and charge transfer capability than SnSe NSs. In addition, it exhibits a superior HER performance in 1.0 M H<subscript>2</subscript>SO<subscript>4</subscript> with overpotential of − 298.79 mV (vs. RHE) at a current density of 10 mA/cm<superscript>2</superscript> and a Tafel slope determined to be only 97.56 mV/dec. Moreover, the SnSe/RGO hybrid as working electrode is provided with excellent durability, which is capable of maintaining working current for 10 h. As demonstrated above, relative high activity and stability and low price make the SnSe/RGO hybrid a promising electrocatalyst. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09478396
Volume :
129
Issue :
6
Database :
Complementary Index
Journal :
Applied Physics A: Materials Science & Processing
Publication Type :
Academic Journal
Accession number :
164396584
Full Text :
https://doi.org/10.1007/s00339-023-06690-2