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Rapid Construction of Hexahydro‐1H‐pyrrolo[3,2‐c]pyridines with Functionalized 1,3‐Enynes and Imines via Palladium Catalysis.
- Source :
- Asian Journal of Organic Chemistry; Jun2023, Vol. 12 Issue 6, p1-4, 4p
- Publication Year :
- 2023
-
Abstract
- Presented herein is a palladium catalyzed tandem reaction between 3‐aminoethyl group tethered 1,3‐enynes and imines, proceeding through a cascade vinylogous addition/reductive elimination/protonation/allylic amination and 1,3‐hydrogen transfer sequence. A collection of complex hexahydro‐1H‐pyrrolo[3,2‐c]pyridine architectures were straightforwardly constructed in moderate yields and diastereoselectivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21935807
- Volume :
- 12
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Asian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 164480857
- Full Text :
- https://doi.org/10.1002/ajoc.202300225