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2-Amino-5-methylpyridinium (2-amino-5-methylpyridine)trichloro-zincate(II).

Authors :
Zhi-Min Jin
Bin Tu
Lin He
Mao-Lin Hu
Jian-Wei Zou
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); Apr2005, Vol. 61 Issue 4, pm197-m199, 3p
Publication Year :
2005

Abstract

The title compound, (C<subscript>6</subscript>H<subscript>9</subscript>N<subscript>2</subscript>)[ZnCl<subscript>3</subscript>(C<subscript>6</subscript>H<subscript>8</subscript>N<subscript>2</subscript>)], consists of one 2-amino-5-methylpyridinium cation and one (2-amino-5-methylpyridine)trichlorozincate(II) anion, which are held together by N—H···Cl hydrogen bonds and π-π interactions. The cation and the pyridine ligand show similar geometric features, except for the N—C bond lengths. Molecules of the title compound are connected by N—H···Cl hydrogen bonds to form chiral chains; these chains are associated further by C—H···C1 hydrogen bonds to form layers, which are in turn linked by π-π interactions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
61
Issue :
4
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
16994594
Full Text :
https://doi.org/10.1107/S0108270105006694