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Reversible structural transformations and color-tunable emissions in organic manganese halides.
- Source :
- Chemical Communications; 9/4/2023, Vol. 59 Issue 68, p10267-10270, 4p
- Publication Year :
- 2023
-
Abstract
- Herein, we for the first time report a reversible conversion between green-emissive [DMPZ]MnCl<subscript>4</subscript> and red-emissive [DMPZ]<subscript>4</subscript>(MnCl<subscript>6</subscript>)(MnCl<subscript>4</subscript>)<subscript>2·</subscript>(H<subscript>2</subscript>O)<subscript>2</subscript> (DMPZ = 1,4-dimethylpiperazine) using kinetic and thermodynamic controlling strategies. Significantly, the synchronous structural and emission transformations in single-component organic manganese halides with adjustable emission colors are highlighted. [ABSTRACT FROM AUTHOR]
- Subjects :
- THERMODYNAMIC control
KINETIC control
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 68
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 170062067
- Full Text :
- https://doi.org/10.1039/d3cc02093b