Rate constants and branching ratios for the dissociative recombination of C3D7+ and C4D9+.

Authors :: Larsson, M.
Ehlerding, A.
Geppert, W. D.
Hellberg, F.
Kalhori, S.
Thomas, R. D.
Djuric, N.
Österdahl, F.
Angelova, G.
Semaniak, J.
Novotny, O.
Arnold, S. T.
Viggiano, A. A.
Source :: Journal of Chemical Physics; 4/15/2005, Vol. 122 Issue 15, p156101, 3p, 2 Charts, 1 Graph
Publication Year :: 2005
Abstract: Product branching ratios and thermal rate coefficients for the dissociative recombination of C<subscript>3</subscript>D<subscript>7</subscript><superscript>+</superscript> and C<subscript>4</subscript>D<subscript>9</subscript><superscript>+</superscript> have been measured in the ion storage ring CRYRING. The results for C<subscript>3</subscript>D<subscript>7</subscript><superscript>+</superscript> are believed to be slightly more accurate than those obtained earlier for C<subscript>3</subscript>H<subscript>7</subscript><superscript>+</superscript>. Only the C–C bond breaking channels could be measured for C<subscript>4</subscript>D<subscript>9</subscript><superscript>+</superscript> and were found to be in excellent agreement with earlier data. [ABSTRACT FROM AUTHOR]

Subjects :: ION recombination
HYDROCARBONS
IONS
SOLUTION (Chemistry)
FREE radical reactions
ELECTRONS

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