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A visible light-driven direct synthesis of industrially relevant glutaric acid diesters from aldehydes.
- Source :
- Chemical Communications; 10/11/2023, Vol. 59 Issue 79, p11875-11878, 4p
- Publication Year :
- 2023
-
Abstract
- A straightforward and practical method has been developed to access α-substituted glutaric diesters from acrylates and aldehydes using visible light, with Eosin Y facilitating hydrogen atom transfer (HAT) and subsequent Giese-type addition. Also, sunlight has been successfully used as an alternative sustainable light source. The method has also been explored to access substituted 4,5-dihydro-2H-pyridazinones, which have potential biological and industrial applications. Comprehensive mechanistic investigations have been carried out. [ABSTRACT FROM AUTHOR]
- Subjects :
- GLUTARIC acid
ABSTRACTION reactions
ALDEHYDES
VISIBLE spectra
LIGHT sources
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 79
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 172783941
- Full Text :
- https://doi.org/10.1039/d3cc02557h