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Homogeneous Iron‐Catalysed Oxidation Of Non‐Activated Alkanes With Hydrogen Peroxide.
- Source :
- ChemCatChem; 10/6/2023, Vol. 15 Issue 19, p1-5, 5p
- Publication Year :
- 2023
-
Abstract
- A novel synthetic protocol for the direct oxidation of alkanes, including cyclic and linear ones, to give ketones and alcohols using hydrogen peroxide as terminal oxidant under ambient conditions is presented. The active catalyst for this challenging transformation is conveniently generated by combination of simple Fe salts with N‐methyl bis(picolylamine) (Me‐bpa). Utilizing picolinic acid as additive leads to improved yields of ketones and alcohols (32‐57 %). The reaction can be conveniently scaled up to multi‐g scale. [ABSTRACT FROM AUTHOR]
- Subjects :
- HYDROGEN peroxide
ALKANES
PICOLINIC acid
OXIDATION
ALCOHOL oxidation
KETONES
Subjects
Details
- Language :
- English
- ISSN :
- 18673880
- Volume :
- 15
- Issue :
- 19
- Database :
- Complementary Index
- Journal :
- ChemCatChem
- Publication Type :
- Academic Journal
- Accession number :
- 172894059
- Full Text :
- https://doi.org/10.1002/cctc.202300735