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Interface Modification via Rare Earth Material to Assist Hole Migration for Efficiency and Stability Promotion of Perovskite Solar Cells.
- Source :
- Solar RRL; Nov2023, Vol. 7 Issue 21, p1-11, 11p
- Publication Year :
- 2023
-
Abstract
- Interface defect is a limiting factor of the charge dynamics and stability of perovskite solar cells (PSCs). Herein, a rare earth metal oxide cerium oxide is introduced into the interface between perovskite and spiro‐OMeTAD [2,2,7,7‐tetrakis (N,N ‐di‐p‐methoxyphenyl‐amine) 9,9‐spirobifluorene] to passivate interfacial defects. Due to the nearest‐neighbor interaction of CeO2 with spiro‐OMeTAD, it can accelerate the oxidization process of spiro‐OMeTAD to form a donor–acceptor complex at this interface, which can overcome the interface barrier for the high hole collecting ability. The bonding formation between lead and oxygen makes this heterojunction show metal conduction behavior at this interface. The insertion of CeO2 between perovskite and spiro‐OMeTAD, can improve hole transferring to balance the extraction of electron and hole by their respective electrodes, for the decreased device hysteresis with the higher efficiency and improved stability. The results show that the CeO2‐based PSC device achieve a power conversion efficiency (PCE) of over 24%, retaining more than 87% of the initial PCE after 2570 h of storage at 20 ≈ 30% humidity. [ABSTRACT FROM AUTHOR]
- Subjects :
- SOLAR cells
CERIUM oxides
PEROVSKITE
CERIUM group
RARE earth oxides
Subjects
Details
- Language :
- English
- ISSN :
- 2367198X
- Volume :
- 7
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Solar RRL
- Publication Type :
- Academic Journal
- Accession number :
- 173397609
- Full Text :
- https://doi.org/10.1002/solr.202300461