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C–H, Si–H and C–F abstraction with an extremely electron poor I(III) reagent.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 11/21/2023, Vol. 52 Issue 43, p15866-15870, 5p
- Publication Year :
- 2023
-
Abstract
- The recently discovered I(III) reagent NO<subscript>2</subscript>-C<subscript>6</subscript>H<subscript>4</subscript>-I(OTf)<subscript>2</subscript> is found to rapidly react with hydride sources, including HSiEt<subscript>3</subscript> and relatively hydridic C–H precursors. These represent the first distinct reactions involving direct hydride abstraction by I(III) under ambient conditions. Direct C–F abstraction is also demonstrated, as well as oxidation of cyclic alkenes to aromatic rings, all representing new reactions for I(III) demonstrating the very high reactivity of NO<subscript>2</subscript>-C<subscript>6</subscript>H<subscript>4</subscript>-I(OTf)<subscript>2</subscript>. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 43
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 173476184
- Full Text :
- https://doi.org/10.1039/d3dt03266c