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A heteropolytungstate based 2D layered porous framework with high proton conductivity.
- Source :
- Chemical Communications; 11/25/2023, Vol. 59 Issue 91, p13627-13630, 4p
- Publication Year :
- 2023
-
Abstract
- A heteropolytungstate cluster [{Ru<subscript>2</subscript>O(bpy)<subscript>2</subscript>}<subscript>2</subscript>{Bi<subscript>2</subscript>W<subscript>32</subscript>O<subscript>110</subscript>}]<superscript>10−</superscript> (bpy = C<subscript>10</subscript>H<subscript>8</subscript>N<subscript>2</subscript>) was incorporated into a 2 : 1 type layered porous framework by interweaving the Na<superscript>+</superscript> bridged cluster chains through the hydrogen bonding ability of the bpy ligands. It features multiple pore channels rich in hydrogen-bond network, contributing high conductivities > 10<superscript>−2</superscript> S cm<superscript>−1</superscript> at 298–358 K and 85% RH. [ABSTRACT FROM AUTHOR]
- Subjects :
- PROTON conductivity
HYDROGEN bonding
PROTONS
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 91
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 173602191
- Full Text :
- https://doi.org/10.1039/d3cc04517j