Schiff base MOFs and their derivatives for sequestration and degradation of pollutants: present and future.

Removal of contaminants via adsorption and catalysis have received a significant interest as energy and money-saving solutions for treating the world's wastewater. Metal–organic frameworks (MOFs), a newly discovered class of porous crystalline materials, have demonstrated tremendous promise in the removal and destruction of contaminants for water purification. In order to improve the interactions of MOFs with the target pollutants for their selective removal and degradation, the Schiff base functionalities emerged as promising active sites. Through pre- and post-synthetic alterations, Schiff base functionalities are integrated into the pore cages of MOF adsorbent materials. To understand the adsorptive/catalytic mechanism, potential interactions between the Schiff base sites and the target pollutants are discussed. Based on cutting-edge techniques for their synthesis, this paper examines current developments in the creation of Schiff base–functionalized MOFs as innovative materials for adsorptive removal and catalytic degradation of contaminants for water remediation. [ABSTRACT FROM AUTHOR]