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Photochemical reductive deamination of alpha-amino aryl alkyl ketones.
- Source :
- Chemical Communications; 12/25/2023, Vol. 59 Issue 99, p14685-14688, 4p
- Publication Year :
- 2023
-
Abstract
- Photochemical reductive deamination of alpha-amino aryl alkyl ketones under photosensitizer-free conditions is presented. This protocol features high efficiency and selectivity. A plausible reaction pathway is proposed based on ultraviolet–visible absorption investigation, control experiments and deuterium-labelling studies. Mechanistic study reveals that the alpha-hydrogen atom of the ketone product originated from water. [ABSTRACT FROM AUTHOR]
- Subjects :
- DEAMINATION
KETONES
ARYLATION
ABSORPTION
ATOMS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 99
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 174178565
- Full Text :
- https://doi.org/10.1039/d3cc04837c