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Pd(OAc)2/Xantphos Catalyzed Reductive Coupling of Sulfonyl Chlorides: Synthesis of Thioethers by Sulphur Dioxide Extrusion.
- Source :
- ChemistrySelect; 12/18/2023, Vol. 8 Issue 47, p1-5, 5p
- Publication Year :
- 2023
-
Abstract
- Herein, we reported a successful cross coupling of aryl sulfonyl chlorides to forge thioether skeleton via Pd catalysis. This transformation proceeded in the presence of Xantphos. Preliminary mechanism studies demonstrated dual roles of Xantphos: (i) a reductant that reduced sulfonyl radical to thio radical; (ii) a ligand that promotes coupling reactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- SULFONYL chlorides
SULFUR dioxide
SULFIDES
ARYL chlorides
SKELETON
Subjects
Details
- Language :
- English
- ISSN :
- 23656549
- Volume :
- 8
- Issue :
- 47
- Database :
- Complementary Index
- Journal :
- ChemistrySelect
- Publication Type :
- Academic Journal
- Accession number :
- 174345921
- Full Text :
- https://doi.org/10.1002/slct.202304571