A Rigorous Derivation of the Water Mass Transformation Framework, the Relation between Mixing and Diasurface Exchange Flow, and Links to Recent Theories in Estuarine Research.

In this paper we present the analytical derivation of a local water mass transformation (WMT) framework for an individual water column. We exactly formulate the mapping of the governing equations from geopotential coordinates to an arbitrary tracer space. Unique definitions for the local effective vertical diasurface fluxes are given. In tracer space we derive new relations between the local diatracer fluxes and the mixing per tracer class. The key relation between the effective vertical diatracer velocity and the mixing per tracer class directly formulates how the overturning circulation is linked to local tracer variance dissipation. Horizontal integration of the governing equations in tracer space and the relations between the diatracer quantities finally recovers the well-known integral WMT formulations. [ABSTRACT FROM AUTHOR]