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21‐Carba‐23‐selenaporphyrinoid Dyads—An Azepine Unit as a Merging Motif.

Authors :
Berlicka, Anna
Foryś‐Martowłos, Paulina
Białek, Michał J.
Stasiak, Katarzyna
Walczak, Aleksandra
Wójcik, Agnieszka
Białońska, Agata
Latos‐Grażyński, Lechosław
Source :
Angewandte Chemie International Edition; Jan2024, Vol. 63 Issue 3, p1-8, 8p
Publication Year :
2024

Abstract

The oxidation of 10,15‐diaryl‐21‐carba‐23‐selenaporphyrinoids resulted in the creation of dyads. The dimerization process follows a [5+2] cycloaddition path with the formation of an azepine unit. The arrays display two direct bonds between the peripheral carbocyclic carbon atoms of one carbaselenaporphyrinic subunit and the central carbon and nitrogen atoms of the second subunit. This results in a unique canted arrangement of two carbaporphyrinoid planes resembling an open seashell‐like motif. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14337851
Volume :
63
Issue :
3
Database :
Complementary Index
Journal :
Angewandte Chemie International Edition
Publication Type :
Academic Journal
Accession number :
174689969
Full Text :
https://doi.org/10.1002/anie.202314925