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Electrochemical decarboxylative alkylation of β-ketoacids with phenol derivatives.
- Source :
- Chemical Communications; 2/4/2024, Vol. 60 Issue 10, p1329-1332, 4p
- Publication Year :
- 2024
-
Abstract
- An electrochemical method for the decarboxylative alkylation of β-ketoacids with phenol derivatives has been developed. The protocol was carried out in readily available unseparated cells at room temperature in the absence of catalysts and oxidants. The corresponding aryl ketones were obtained in satisfactory yields without additional electrolytes, and were easy to produce in gram-scale synthesis. Based on control experiments and cyclic voltammetry, a plausible reaction mechanism was proposed. [ABSTRACT FROM AUTHOR]
- Subjects :
- ALKYLATION
CYCLIC voltammetry
OXIDIZING agents
ELECTROLYTES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 175142122
- Full Text :
- https://doi.org/10.1039/d3cc05489f