Fs Laser Patterning of Amorphous As 2 S 3 Thin Films.

This study investigates the morphological changes induced by femtosecond (fs) laser pulses in arsenic trisulfide (As₂S₃) thin films and gold–arsenic trisulfide (Au\As₂S₃) heterostructures, grown by pulsed laser deposition (PLD). By means of a direct laser writing experimental setup, the films were systematically irradiated at various laser power and irradiation times to observe their effects on surface modifications. AFM was employed for morphological and topological characterization. Our results reveal a clear transition threshold between photoexpansion and photoevaporation phenomena under different femtosecond laser power regimes, occurring between 1 and 1.5 mW, irrespective of exposure time. Notably, the presence of a gold layer in the heterostructure minimally influenced this threshold. A maximum photoexpansion of 5.2% was obtained in As₂S₃ films, while the Au\As₂S₃ heterostructure exhibited a peak photoexpansion of 0.8%. The study also includes a comparative analysis of continuous-wave (cw) laser irradiation, confirming the efficiency of fs laser pulses in inducing photoexpansion effects. [ABSTRACT FROM AUTHOR]