Up-converted white light emission in Er3+ doped MgAl2O4 nanocrystals.

This work presents the influence of host defect centers on the photoluminescence characteristics of Mg 1 − x Er x Al 2 O 4 (x = 0.005, 0.01, and 0.03) nanocrystals under UV and near-infrared (NIR) excitations. The spinel-structured nanocrystals are synthesized through the combustion method. The Rietveld refinement and nuclear magnetic resonance analyses estimated the Er 3 + ion occupancy at octahedral and other random sites of the MgAl 2 O 4 lattice, and the existence of various lattice defects. Diffuse reflectance spectra showed broad bands attributed to oxygen vacancies as well as antisite defects and sharp peaks attributed to f–f transitions of Er 3 + ions. The upconversion luminescence spectra consisted of sharp emission lines, ascribed to Er 3 + ions, in the green and red wavelength regions, which overlapped over the broad curve attributed to intrinsic defects. Further, the UV excited downconversion luminescence spectra showed two broad emission bands in blue–violet and red-NIR regions with a very weak Er 3 + ion emission feature. This up- and downconversion emission revealed energy transfer between host and Er 3 + ions via intrinsic defects. As a result, the emission color changes from bluish purple to white by varying the excitation wavelength from UV to NIR. This rare earth activated luminescence from MgAl 2 O 4 nanocrystals would exhibit potential applications in display devices and solid-state lighting. [ABSTRACT FROM AUTHOR]