Oxidative Conversion of Polyethylene Towards Di‐Carboxylic Acids: A Multi‐Analytical Approach.

To reduce the pressure on the environment created by the increasing amount of plastic waste, the need to develop suitable plastic recycling methods has become more evident. However, the chemical recycling toolbox for polyethylene (PE), the most abundant type of plastic waste, remains underdeveloped. In this work, analytical methods were developed to explore the possibility to oxidatively convert PE into di‐carboxylic acids as reaction products. A multi‐analytical approach including gas chromatography‐mass spectrometry, gas chromatography‐flame ionization detection, several (2D) nuclear magnetic resonance methods as well as in‐situ transmission infrared spectroscopy was used. This led to a thorough qualitative and quantitative analysis on the product mixture, which extends and clarifies the existing literature. Without a catalyst (thermally) already up to 7 mol % di‐carboxylic acids can be formed. Furthermore, it was found that the majority of the oxidized functionalities are carboxylic acids, (methyl) ketones, γ‐lactones, γ‐ketones and esters. An intra‐molecular hydrogen shift seemed key in the cleavage step and the formation of late‐stage side products. In addition, crosslinking reactions due to esterification reactions seem to limit the di‐carboxylic acid yield. Therefore, these two handles can be taken into account to study and design similar (catalytic) systems for the oxidative conversion of plastic waste. [ABSTRACT FROM AUTHOR]