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Nucleation-Controlled Production of Sub-50 nm Carbon Nanotubes through Electrochemical Conversion of Carbon Dioxide in Carbonate Molten Salt.
- Source :
- International Journal of Energy Research; 4/24/2024, Vol. 2024, p1-10, 10p
- Publication Year :
- 2024
-
Abstract
- The increasing emission of carbon dioxide worldwide has emerged as a major global concern in the context of addressing climate change. Converting CO<subscript>2</subscript> to high-value carbon materials is a promising solution to capture emitted carbon for achieving carbon neutrality. Furthermore, such conversion can provide carbon nanomaterials for key industries, including the lithium battery and fuel cell industries. Here, it is shown that sub-50 nm tangled carbon nanotubes (CNTs) can be synthesized by adjusting the metaborate concentration and the current density through the electrochemical conversion of carbon dioxide in a molten carbonate salt. The metaborate ion concentration affects the product selectivity and carbon morphology, and the current density is strongly related to the particle size of in situ seed catalysts supplied by the dissolution of an Ni-Fe-Cr alloy anode. The optimized process conditions control the nucleation and growth of carbon via a tip-growth mechanism, thereby promoting the formation of sub-50 nm CNTs rather than bulky irregular carbon particles. The Raman and Brunauer–Emmett–Teller analyses showed that the properties of the prepared CNTs depended on the synthetic parameters. This study provides deep insights into the mechanism underlying carbon synthesis through the electrochemical reduction of a molten carbonate salt. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0363907X
- Volume :
- 2024
- Database :
- Complementary Index
- Journal :
- International Journal of Energy Research
- Publication Type :
- Academic Journal
- Accession number :
- 176846933
- Full Text :
- https://doi.org/10.1155/2024/6616423