Back to Search
Start Over
Application of Sulfoxonium Ylides or Iodonium Ylides in Rhodium‐Catalyzed Synthesis of Phenanthrenes.
- Source :
- Advanced Synthesis & Catalysis; Apr2024, Vol. 366 Issue 8, p1744-1750, 7p
- Publication Year :
- 2024
-
Abstract
- The transmetalation triggered rhodium‐catalyzed C−H bond activation and tandem annulation of 2‐biphenylboronic acids with sulfoxonium ylides or iodonium ylides has been developed. Various products of phenanthrenes were constructed under redox‐neutral conditions in 34–86% yields. Several mechanism exploration experiments and derivatization reactions were conducted in sequence to gain a deeper understanding of the process and the potential of this transformation. It offers an alternative approach for the synthesis of phenanthrene derivatives. [ABSTRACT FROM AUTHOR]
- Subjects :
- YLIDES
PHENANTHRENE derivatives
PHENANTHRENE
ANNULATION
DERIVATIZATION
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 366
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 176868022
- Full Text :
- https://doi.org/10.1002/adsc.202301451