Recovery of Cobalt, Nickel, and Lithium from Spent Lithium-Ion Batteries with Gluconic Acid Leaching Process: Kinetics Study.

The demand for lithium-ion batteries (LIBs) is driven by environmental concerns and market growth, particularly in the transportation sector. The EU's push for net-zero emissions and the European Green Deal accentuates the role of battery technologies in sustainable energy supply. Organic acids, like gluconic acid, are explored for the eco-friendly leaching of valuable metals from spent batteries. This study investigates leaching kinetics using gluconic acid (hydrolyzed glucono-1.5-lacton), analyzing factors such as temperature, acid concentration, particle size, and reaction time. Results reveal the temperature's influence on leaching efficiency for cobalt, nickel, and lithium. The mechanism for Co follows a surface chemical reaction model with an activation energy of 28.2 kJ·mol⁻¹. Nickel, on the contrary, shows a diffusion-controlled regime and an activation energy of 70.1 kJ·mol⁻¹. The reaction of leaching Ni and Co using gluconic acid was determined to be first-order. The process within this environmentally friendly alternative leaching agent shows great potential for sustainable metal recovery. [ABSTRACT FROM AUTHOR]