Separation of ReO4−/TcO4− from simulated radioactive waste liquid by a novel series of anion exchange resins.

Selective removal of ⁹⁹TcO₄⁻ from radioactive wastewater is a challenging but significant task, which benefits spent fuel reprocessing and radioactive-waste leakage treatment. This work introduces the performance of adsorption ReO₄⁻ using a series of novel anion exchange resins, namely MAPE-1, MAPE-2, MAPE-3, and MAGD-1, impregnated with functionalized ionic liquids as active sites. They exhibit a high selectivity towards TcO₄⁻/ReO₄⁻, in a wide pH range of pH 5–11 for ReO₄⁻/TcO₄⁻ adsorption. Among these resins, MAPE-1 has the best adsorption performance for ReO₄⁻, with a maximum adsorption capacity of 202.4 mg/g and a high distribution ratio K_d of 6.2 × 10⁶ mL/g at pH 7. The adsorption mechanism involves anion exchange between functionalized ionic liquids and TcO₄⁻/ReO₄⁻, which is supported by X-ray energy dispersive spectroscopy (EDS) and Fourier Transform Infrared spectroscopy (FT-IR) analyses. In addition, X-ray photoelectron spectroscopy (XPS) further illustrates the interaction between the resin and perrhenate. [ABSTRACT FROM AUTHOR]