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Perylene with peripherally fused pyrrole and pyridine: columnar packing, anti-Kasha dual emission and reactive oxygen species generation.
- Source :
- New Journal of Chemistry; 5/28/2024, Vol. 48 Issue 20, p9014-9019, 6p
- Publication Year :
- 2024
-
Abstract
- Simultaneously fusing pyrrole and pyridine at perylene's opposite edges is facilely achieved in this work, yielding PerNN and its various derivatives. All targets demonstrate global diamagnetic ring current. Benefiting from a spatially separated donor–acceptor group within one planar skeleton, PerNN exhibits efficient narrow blue emission and columnar stacking. More importantly, its alkylated derivatives PerNN-MeCl and PerNN-MeI display anti-Kasha dual emission responsive to solvent polarity and reveal highly efficient ROS generation, paving the way to great potential applications. [ABSTRACT FROM AUTHOR]
- Subjects :
- REACTIVE oxygen species
PYRROLES
PYRIDINE
BISIMIDES
PERYLENE
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 48
- Issue :
- 20
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177354131
- Full Text :
- https://doi.org/10.1039/d4nj01177e