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Heteroatom‐Promoted Polyhexagonal Saddle‐Shaped Molecular Structures and their Supramolecular Coassembly with C60.
- Source :
- Chemistry - A European Journal; 6/3/2024, Vol. 30 Issue 31, p1-8, 8p
- Publication Year :
- 2024
-
Abstract
- Molecules with curved architecture can exhibit unique optoelectronic properties due to the concave‐convex π‐surface. However, synthesizing negatively curved saddle‐shaped aromatic systems has been challenging due to the internal structural strain. Herein, we report the facile synthesis of two polyhexagonal molecular systems, 1 and 2, with saddle shape geometry by judiciously varying the aromatic moiety, avoiding the harsh synthetic methods as that of heptagonal aromatic saddle systems. The unique geometry preferences of B, N, and S furnish suitable curvature to the molecules, featuring saddle shape. The saddle geometry also enables them to interact with fullerene C60, and the supramolecular interactions of fullerene C60 with 1 and 2 modify their optoelectronic properties. Crystal structure analysis reveals that 1, with a small π‐surface, forms a double columnar array of fullerenes in the solid state. In contrast, 2 with a large π‐surface produces a supramolecular capsule entrapping two discrete fullerenes. The intermolecular interactions between B, N, S, and the aryl‐π surface of the host and C60 guest are the stabilizing factors for creating these supramolecular structures. Comprehensive computational, optical, and Raman spectroscopic studies establish the charge transfer interactions between B−N doped heterocycle host and fullerene C60 guest. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 30
- Issue :
- 31
- Database :
- Complementary Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 177627588
- Full Text :
- https://doi.org/10.1002/chem.202400398