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Heterojunction interface engineering for stable and effective porous Fe3O4-ZnO nanocomposites: a highly efficient synergistic catalyst for oxygen evolution reaction.

Authors :
Shanmugapriya, S. A. T.
Kumar, Anand
Mondal, Aniruddha
Afzal, Mohd
Mondal, Sudip
Source :
Chemical Papers; Jun2024, Vol. 78 Issue 8, p4699-4708, 10p
Publication Year :
2024

Abstract

The development of renewable energy technologies, such as fuel cells and metal-air batteries, relies heavily on the availability of highly efficient electrocatalysts for the oxygen evolution reaction (OER). In this study, a mesoporous Fe<subscript>3</subscript>O<subscript>4</subscript>-ZnO nanocomposites was synthesized using a simple and economically viable approach at a relatively low temperature. The observed catalytic activity of the prepared Fe<subscript>3</subscript>O<subscript>4</subscript>-ZnO nanocomposites mesoporous nanostructure was found to be remarkable. Additionally, the nanostructure exhibited a high tolerance to methanol and demonstrated durability towards oxygen evolution reaction (OER) in alkaline media. In the course of the experiment, it was observed that the catalyst exhibited noteworthy activity in the oxygen evolution reaction (OER) when compared to the commercially available RuO<subscript>2</subscript> catalyst. This was evident through a more negative onset potential and higher current. The catalyst's notable capacity for high oxygen reaction activity may potentially enhance the synergistic effect resulting from the combination of defect sites and the porous structure of Fe<subscript>3</subscript>O<subscript>4</subscript>-ZnO nanocomposites. The findings of this study indicate that the Fe<subscript>3</subscript>O<subscript>4</subscript>-ZnO nanocomposites exhibit promising attributes as an electrocatalyst with overpotential and Tafel slope value of 350 mV and 62 mVdec<superscript>−1</superscript> for the oxygen evolution reaction (OER) in real-world scenarios. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03666352
Volume :
78
Issue :
8
Database :
Complementary Index
Journal :
Chemical Papers
Publication Type :
Academic Journal
Accession number :
178027419
Full Text :
https://doi.org/10.1007/s11696-024-03401-w