On the Budget and Atmospheric Fate of Sulfur Emissions From Large Volcanic Eruptions.

Today, volcanic sulfur emissions into the atmosphere are measured spectroscopically from the ground, air and space. For eruptions prior to the satellite era, two main sulfur proxies are used, the rock and ice core records, as illustrated by Peccia et al. (2023, https://doi.org/10.1029/2023gl103334). The first approach is based on calculations of the sulfur content of the magma, while the second uses traces of sulfur deposited in ice. Both approaches have their limitations. For glaciochemistry, the volcano responsible for a sulfur anomaly is often unknown and the atmospheric pathway by which the sulfur reached the ice uncertain. The petrologic method relies, too, on uncertain estimates of eruption size and a number of geochemical assumptions that are hard to verify. A deeper knowledge of processes occurring both within magma bodies prior to eruption, and within volcanic plumes in the atmosphere is needed to further our understanding of the impacts of volcanism on climate. Plain Language Summary: Volcanic emissions of sulfur gases during large eruptions can change the global climate. Today, advanced spectroscopic tools allow us to measure sulfur from the ground, air and space. But to understand the impacts of volcanic activity on climate back through history we need to estimate volcanic sulfur releases in other ways. Clues can be found in the pumice deposits found around a volcano and, perhaps more surprisingly, in the ice caps of the polar regions, which receive the eventual fallout from large eruptions. Both approaches have limitations that are addressed in a recent work by Peccia et al. (2023, https://doi.org/10.1029/2023gl103334) and that are at the focus of our commentary. Key Points: The impact of volcanic activity on climate remains difficult to quantify for eruptions prior to the instrumental eraThe petrological and glaciochemical methods each provide answers, but are still fraught with large uncertaintiesWe need to further our understanding of the physicochemical processes occurring both within magma reservoirs and volcanic plumes [ABSTRACT FROM AUTHOR]