Tailored BiPO4/Bi‐MOF heterostructure photocatalysts with diverse morphologies for highly efficient organic pollutant degradation.

Three distinct morphologies of Bi‐MOFs were innovatively employed as carriers, facilitating the formation of heterojunctions with BiPO4. Among these, the optimal photocatalytic performance was demonstrated by the type II heterojunction BiPO4/CAU‐17. Bi3+ competitively coordinated to crucially aid CAU‐17's transformation into a heterojunction, enhancing interfacial contact in BiPO4/CAU‐17. These photocatalysts effectively degraded dyes (RhB, MO, MB) and tetracycline (TC) under light exposure. RhB degradation was 3.33 times faster with BiPO4/CAU‐17 than BiPO4, 1.45 times faster than FCAU‐17, 1.36 times faster than FRCAU‐17, and 1.32 times faster than CAU‐17. Analyzing carrier density, Fermi level, and band structure through VB‐XPS, UV–VIS, and Mott–Schottky provided insights into enhanced separation of photoexcited electron–hole pairs. This study presents a novel approach to tackle the aggregation challenge of the wide‐bandgap material BiPO4 by using suitable MOFs as carriers. It offers valuable perspectives for the design and application of photocatalysts in environmental remediation. [ABSTRACT FROM AUTHOR]