Unlocking the Myths of Molecular Bonding State in Modulating Oxidation and Anderson Localization for Inorganic Sn/Pb‐based Perovskite Solar Cells.

The improvement of photovoltaic and stability performance of tin (Sn)‐based halide perovskite solar cells is impeded by notorious oxidation issues and Anderson localization. Despite previous implements in antioxidation through the incorporation of Lewis base additives, there still exist ongoing uncertainties surrounding its complex interaction mechanisms. A perplexing phenomenon regarding accelerated oxidation in acrylic acid is discovered that deviates from conventional Lewis base–acid reaction. The underlying insights into the deprotonation of acrylic acid followed by the formation of a "tripod" ionic bonding form are provided, which results in amplifying the delocalization effect of electrons of Sn2+. Furthermore, with the assistance of acrylamide and acrolein, synergistic enhancement in terms of the antioxidation and suppression of Anderson localization can be achieved — a concept referred to as "Dual Synergistic Engineering". This suppresses the oxidation of Sn2+ and reduces Sn4+ content by ≈76%. Meanwhile, the diffusion length is prolonged significantly from 195.9 to 458.9 nm. The optimized all‐inorganic Sn/Pb‐based perovskite solar cells exhibit a power conversion efficiency of above 14% with enhanced stability. These findings provide an alternative viewpoint for comprehending the impact of chemical interaction on oxidation and crystal growth in Sn/Pb‐based perovskites. [ABSTRACT FROM AUTHOR]