Efficient deep-blue electroluminescence from Ce-based metal halide.

Rare earth ions with d-f transitions (Ce³⁺, Eu²⁺) have emerged as promising candidates for electroluminescence applications due to their abundant emission spectra, high light conversion efficiency, and excellent stability. However, directly injecting charge into 4f orbitals remains a significant challenge, resulting in unsatisfied external quantum efficiency and high operating voltage in rare earth light-emitting diodes. Herein, we propose a scheme to solve the difficulty by utilizing the energy transfer process. X-ray photoelectron spectroscopy and transient absorption spectra suggest that the Cs₃CeI₆ luminescence process is primarily driven by the energy transfer from the I₂-based self-trapped exciton to the Ce-based Frenkel exciton. Furthermore, energy transfer efficiency is largely improved by enhancing the spectra overlap between the self-trapped exciton emission and the Ce-based Frenkel exciton excitation. When implemented as an active layer in light-emitting diodes, they show the maximum brightness and external quantum efficiency of 1073 cd m⁻² and 7.9%, respectively. Rare-earth metal halide perovskites are promising for deep blue LEDs. Here, Yang et al. report energy transfer between self-trapped exciton and Frenkel exciton in Cs3CeI6 by adding excess CsI during thermal evaporation, resulting in deep blue LEDs with external quantum efficiency of 7.9% at 424 nm. [ABSTRACT FROM AUTHOR]