Space Weather Induces Changes in the Composition of Atmospheric Escape at Mars.

Mars' dayside ionosphere is maintained primarily by ionization from solar ultraviolet photons and subsequent chemical reactions, with small contributions from other mechanisms such as impact ionization and charge exchange. In December 2023, the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission observed the impact of an interplanetary coronal mass ejection (ICME) on Mars' ionosphere, including strongly enhanced fluxes of suprathermal electrons. We show that this enhancement in suprathermal electron fluxes increased ion production from electron impact, so that dayside electron impact ionization rates exceeded photoionization rates during the ICME. This change in ion production mechanisms led to unusually high densities of the minor ions C+ ${\mathrm{C}}^{+}$ and O++ ${\mathrm{O}}^{++}$. Space weather events are known to increase ion escape rates, so changes in ion composition during space weather events have important implications for atmospheric evolution. We show that scaling nominal loss rates to account for space weather may underestimate carbon loss from Mars' atmosphere. Plain Language Summary: Dayside planetary ionospheres are primarily produced through interactions between atmospheric neutral gases and sunlight. Impact by energetic particles, especially electrons, typically only contributes a small amount of plasma. We observed unusually high densities of the minor ions C+ ${\mathrm{C}}^{+}$ and O++ ${\mathrm{O}}^{++}$ in Mars' ionosphere during a space weather event in December 2023, when a large bubble of magnetized plasma launched from the Sun impacted the planet. This plasma bubble compressed the Mars magnetosheath, pushing suprathermal electrons to lower altitudes, where they impacted the atmosphere and significantly increased plasma production through impact ionization. Changes in the production mechanisms of the ionosphere during space weather events lead to changes in its density and composition. This is important because space weather events are known to increase the amount of atmospheric gas escaping from a planet, which can have important implications for how the atmosphere evolves over millions of years. Key Points: Unexpected increases in C+ and rarely detected O++ densities were observed during the December 2023 space weather event at MarsThese ions were produced by electron impact ionization from the intense electron fluxes associated with the space weather eventElectron impact ionization exceeded photoionization during the event, which temporarily altered the composition of ions escaping Mars [ABSTRACT FROM AUTHOR]