Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant.

Four metalloporphyrinic metal–organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH₂(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation. [ABSTRACT FROM AUTHOR]