The Influence of Monofunctional Silanes on the Mechanical and Rheological Properties of Hot Melt Butyl Rubber Sealants.

The influence of organosilicon compounds on butyl sealant blends' mechanical and processing properties was investigated, particularly under increased humidity conditions. The addition of (3-mercaptopropyl)trimethoxysilane (MPTES), (3-aminopropyl)triethoxysilane (APTES), vinyltrimethoxysilane (VTMOS), and (3-glycidoxypropyl)trimethoxysilane (GLYMO) to elastomeric blends containing butyl rubber (IIR) and polyisobutylene (PIB) was studied. Key rheological parameters, including Mooney viscosity and melt volume rate (MVR), along with mechanical attributes such as peel resistance and cone penetration, were evaluated. Results indicated that functionalized silanes enhance sealant cohesion when their functional groups interact with the matrix and form cross-links under humid conditions. The presence of unreacted silanes acts as a plasticizer, increasing MVR and reducing viscosity. A notable MVR increase, up to 109 mL/10 min, was observed for the APTES-10 system. The most significant mechanical property enhancements were observed in blends containing MPTES and APTES, resulting in increased cohesion and peel resistance. The findings of this research are of considerable practical relevance, demonstrating that the modification of rubber sealants with monofunctional silanes improves their cohesion, delamination resistance, and processability, thereby making these materials suitable for the production of more durable sealants. [ABSTRACT FROM AUTHOR]