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1,4-Dimethyl-1,4-diazo­nia­bicyclo­[2.2.2]octane diiodide acetonitrile solvate.

Authors :
Janzen, Daron E.
Ewbank, Paul C.
Mann, Kent R.
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); Nov2005, Vol. 61 Issue 11, po631-o633, 3p
Publication Year :
2005

Abstract

In the crystal structure of the title compound, C<subscript>8</subscript>H<subscript>18</subscript>N<subscript>2</subscript><superscript>2+</superscript>·2I<superscript>−</superscript>·CH<subscript>3</subscript>CN, the dication lies on a mirror plane containing the mol­ecular dication threefold axis. The structure displays C—H⋯I inter­actions between H atoms of the 1,4-dimethyl-1,4-diazo­nia­bicyclo­[2.2.2]octane dication and the iodide anions. The H⋯I distances are in the range 2.96–3.18 (4) Å. The dications pack forming channels along the b axis, which contain the iodide anions and acetonitrile solvent mol­ecules. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
61
Issue :
11
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
18786671
Full Text :
https://doi.org/10.1107/S0108270105028763