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New Type of an Adsorption Layer of Organic Molecules with a Cage Structure Condensed at the Electrode/Solution Interface: The Adsorption of Cubane Derivatives on a Mercury Electrode.
- Source :
- Russian Journal of Electrochemistry; Oct2003, Vol. 39 Issue 10, p1017-1024, 8p
- Publication Year :
- 2003
-
Abstract
- A synthesis and a study by method of measuring the differential capacitance on a stationary mercury drop of the adsorption of a number of cubane derivatives in a surface-inactive electrolyte are performed. It is established that the compounds studied exhibit a high surface activity. For bromine derivatives of cubane (4-bromomethoxycarbonylcubane, 4-bromohydroxymethylcubane) the formation of two-dimensional adsorption layers is discovered. Values of adsorption parameters for these compounds are evaluated with use made of the Frumkin isotherm. [ABSTRACT FROM AUTHOR]
- Subjects :
- ADSORPTION (Chemistry)
MOLECULES
ELECTRODES
MERCURY
Subjects
Details
- Language :
- English
- ISSN :
- 10231935
- Volume :
- 39
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Russian Journal of Electrochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 22101322