Synthesis and Structural Characterization of A Single Crystal of [Na2(H2O)10](NH4)3(NH3)[MoV9O28].

Authors :: Wang, Shou‐Jiang
Dong, Wen‐Kui
Chen, Yan‐Mei
Source :: Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry; 2006, Vol. 36 Issue 9, p649-653, 5p, 2 Diagrams, 2 Charts
Publication Year :: 2006
Abstract: A novel compound with the formula [Na2(H2O)10](NH4)3(NH3)[MoV9O28] has been synthesized for the first time and characterized by single crystal X‐ray diffraction, infrared spectrum, UV spectrum, element analysis and ICP analysis. The complex crystallizes in the triclinic space group P-1, with a=0.864 5(4) nm, b=1.044 8(4) nm, c=1.122 7(5) nm, α=69.245(6)°, β=87.224(6)°, γ=66.762(5)° and Z=1. The structure of the anion [MoV9O28]5- has a molybdenum atom mixing with nine vanadium atoms at certain positions in the similar backbone of the decanucleus structure. [ABSTRACT FROM AUTHOR]

Subjects :: MOLYBDENUM compounds
VANADIUM
X-ray diffraction
INFRARED spectra
ULTRAVIOLET spectra
BIOCHEMISTRY

Language :: English
ISSN :: 15533174
Volume :: 36
Issue :: 9
Database :: Complementary Index
Journal :: Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
Publication Type :: Academic Journal
Accession number :: 22976686
Full Text :: https://doi.org/10.1080/15533170600962406

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