Back to Search
Start Over
Synthesis and Structural Characterization of A Single Crystal of [Na2(H2O)10](NH4)3(NH3)[MoV9O28].
- Source :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry; 2006, Vol. 36 Issue 9, p649-653, 5p, 2 Diagrams, 2 Charts
- Publication Year :
- 2006
-
Abstract
- A novel compound with the formula [Na2(H2O)10](NH4)3(NH3)[MoV9O28] has been synthesized for the first time and characterized by single crystal X‐ray diffraction, infrared spectrum, UV spectrum, element analysis and ICP analysis. The complex crystallizes in the triclinic space group P-1, with a=0.864 5(4) nm, b=1.044 8(4) nm, c=1.122 7(5) nm, α=69.245(6)°, β=87.224(6)°, γ=66.762(5)° and Z=1. The structure of the anion [MoV9O28]5- has a molybdenum atom mixing with nine vanadium atoms at certain positions in the similar backbone of the decanucleus structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15533174
- Volume :
- 36
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 22976686
- Full Text :
- https://doi.org/10.1080/15533170600962406