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Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates.

Authors :
Motoi Kawatsura
Fumio Ata
Shohei Wada
Shuichi Hayase
Hidemitsu Uno
Toshiyuki Itoh
Source :
Chemical Communications; Jan2007, Vol. 2007 Issue 3, p298-300, 3p
Publication Year :
2007

Abstract

The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru3(CO)12 with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
2007
Issue :
3
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
23626963
Full Text :
https://doi.org/10.1039/b614015g