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Silver-catalyzed [2,3]-rearrangement of halonium ylides derived from allyl and propargyl halides and alkyl diazoacetates.
- Source :
- Chemical Communications; Feb2007, Vol. 2007 Issue 7, p731-733, 3p
- Publication Year :
- 2007
-
Abstract
- A silver(i) complex derived from a polyfluorinated tris(pyrazolyl)borate effectively catalyzes carbene transfer to allylic and propargylic halides, leading to the formation of α-haloacetate derivatives. [ABSTRACT FROM AUTHOR]
- Subjects :
- YLIDES
IONS
ALLYL halides
PRECIOUS metals
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2007
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 23969900