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Magnetic canting or not? Two isomorphous 3D CoII and NiII coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the CoII system.
- Source :
- Chemical Communications; May2007, Vol. 2007 Issue 22, p2290-2292, 3p
- Publication Year :
- 2007
-
Abstract
- The in situ solvothermal reaction of 3,4-dicyano-1,2,5-thiadiazole with MCl2 (M = Co, Ni) and NaOH afforded two isomorphous complexes, [M2(L)2(H2O)2]n (L = 2,1,3-thiadiazole-4,5-dicarboxylate), which exhibit a rare non-interpenetrated (10,3)-d (utp) network topology and interesting magnetic behaviors: spin-canted antiferromagnetism for the CoII complex, but simple antiferromagnetic coupling for the NiII. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2007
- Issue :
- 22
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 25322672
- Full Text :
- https://doi.org/10.1039/b700569e