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Carbon Combustion Synthesis and Magnetic Properties of Cobalt Ferrite Nanoparticles.

Authors :
Martirosyan, Karen S.
Chang, Long
Rantschler, James
Khizroev, Sakhrat
Luss, Dan
Litvinov, Dmitri
Source :
IEEE Transactions on Magnetics; Jun2007, Vol. 43 Issue 6, p3118-3120, 3p, 1 Black and White Photograph, 4 Graphs
Publication Year :
2007

Abstract

Cobalt ferrite CoFe<subscript>2</subscript> O<subscript>4</subscript> crystalline nanoparticles (50-100 nm) were produced by carbon combustion synthesis of oxides (CCSO). In this combustion synthesis process, the exothermic oxidation of carbon generates a thermal reaction wave that propagates through the solid reactants mixture of CoO and Fe<subscript>2</subscript> O<subscript>3</subscript> converting it to cobalt ferrite. The extensive emission of CO<subscript>2</subscript> increased the porosity and friability of the product. The quenching front method combined with XRD and VSM characterization revealed that crystalline CoFe<subscript>2</subscript> O<subscript>4</subscript> particles formed in the early stage of the combustion, before the temperature reached its maximum. The maximum value of the coercivity of the quenched product within the front region was 940 Oe with a magnetization of 15 emu/g. The as-synthesized ferrites had hard magnetic properties with coercivity of 700 Oe and saturation magnetization of up to 47 emu/g. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00189464
Volume :
43
Issue :
6
Database :
Complementary Index
Journal :
IEEE Transactions on Magnetics
Publication Type :
Academic Journal
Accession number :
25328834
Full Text :
https://doi.org/10.1109/TMAG.2007.893844