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Responsive fluorinated lanthanide probes for 19F magnetic resonance spectroscopy.

Authors :
P. Kanthi Senanayake
Alan M. Kenwright
David Parker
Susanna K. van der Hoorn
Source :
Chemical Communications; Jul2007, Vol. 2007 Issue 28, p2923-2925, 3p
Publication Year :
2007

Abstract

The introduction of CF3 reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of 19F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
2007
Issue :
28
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
25751632
Full Text :
https://doi.org/10.1039/b705844f